Rotational Spectroscopy of Diatomic Molecules

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April 2003



Diatomic molecules are important to the physical sciences because they are the basic building blocks of large molecules. Many of the principles which underly our understanding of chemical bonds in molecules were first developed by studying diatomic systems. Starting from fundamental principles, this book develops a theory that analyzes the energy levels of diatomic molecules and summarizes the many experimental methods used to study the spectra of these molecules in the gaseous state.


1. General introduction; 2. The separation of nuclear and electronic motion; 3. The electronic hamiltonian; 4. Interactions arising from nuclear magnetic and electric moments; 5. Angular momentum theory and spherical tensor algebra; 6. Electronic and vibrational states; 7. Derivation of the effective hamiltonian; 8. Molecular beam magnetic and electric resonance; 9. Microwave and far-infrared magnetic resonance; 10. Pure rotational spectroscopy; 11. Double resonance spectroscopy; Appendices.


Professor of Chemistry in the Physical and Theoretical Chemistry Laboratory at the University of Oxford. Emeritus Professor of Chemistry at the University of Southampton.


'... the authors are to be congratulated on producing an updates, valuable and comprehensive review of the field.' ChemPhysChem
EAN: 9780521530781
ISBN: 0521530784
Untertitel: 'Cambridge Molecular Science'. 295 b/w illus. 74 tables. Sprache: Englisch.
Verlag: Cambridge University Press
Erscheinungsdatum: April 2003
Seitenanzahl: 1046 Seiten
Format: kartoniert
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