Synthesis and Characterization of Mn+2, Co+2, Ni+2, Cu+2 and Zn+2
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BeschreibungResearch Paper from the year 2012 in the subject Chemistry - Anorganic Chemistry, University of Mosul (Dental college), language: English, abstract: A series of new complex salts of the type [A]2[MCl2I2] where A=1,3,5-trimethylpyridinium cation, M= Mn+2,Co+2, Ni+2,Cu+2 and Zn+2 were prepared by the reaction of the metal chloride and 1,3,5-trimethylpyridinium iodide in (1:2) molar ratio and characterized by elemental analysis, molar conductance, IR, Uv/Vis., spectral studies and magnetic measurements. The crystal structure of 1,3,5-trimethylpyridinuim iodide was determined by single crystal x-ray crystallography. The structure of the anion part and a 1,3,5- trimethylpyridinium cation which crystallizes in the orthorhombic space group (Cmcm) with a=8.9850(9), b=15.767(2), c=6.9940(6)A°, V=990.82 (16)A°, Z=4. Which is on a crystallographic mirror plane perpendicular to C-axis except for methyl hydrogen atoms. The anion and cation are connected through hydrogen bonds between I and the cation by hydrogen bonding, electrostatic interaction and weak ¿-¿ interaction are also expected.
PortraitName: AMER A. TAQA Email: email@example.com DEPARTMENT OF DENTAL BASIC SCIENCE COLLEGE OF DENTISTRY/MOSUL UNIVERSITY/IRAQ EDUCATION PhD in Inorganic Chemistry awarded in 2001. Dissertation Title " Preparation and study some of complexes that can be used as dental restorative. Advisor: Tahanee Al-Sandook and I.M.Ahmed. M.Sc in inorganic Chemistry awarded in 1991. Dissertation Title" Preparation and study some of uranium complexes with nitrones" Advisor: Wiseman Aziz. B.Sc in Chemistry awarded in 1985. EXPERIENCE Professor teaching in Dental Basic Science Mosul University 1993-to present. Head of Dept. of Dental Basic Sciences ¿ 2003 to 2005 Registrar of Dept. of Dental Basic Sciences -1995 to 2003 Professor 2009 Assistant Professor - 1999 Lecturer 1995 Assistant lecturer 1993 Postgraduate MSc Supervision Student in an inorganic Chemistry in Science College. Seven students in Prosthetic in Dentistry College. One student in orthodontic in Dental College. Three students in Operative in Dental College.
Untertitel: Sprache: Englisch. Dateigröße in KByte: 826.
Verlag: GRIN Verlag
Erscheinungsdatum: Februar 2013
Seitenanzahl: 12 Seiten
Format: pdf eBook