Scorpionates: The Coordination Chemistry of Polypyrazolylborate Ligands

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August 1999



This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966 but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their "Bite" can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 120 different scorpionate ligands are known today, and some, are published for the first time in this book.


"This important book, laden with chemical facts, is useful and well written ... Exhaustive coverage of scorpionate ligands establishes this book as the definitive source for anyone considering any aspect of scorpionate chemistry." J. Am. Chem. Soc., 2000 "This book is essential for every researcher who makes use of Tp ligands and wishes to avoid duplicating work that has already been reported." Angew. Chem. Int. Ed., 2000
EAN: 9781860941726
ISBN: 1860941729
Untertitel: New. Sprache: Englisch.
Erscheinungsdatum: August 1999
Seitenanzahl: 292 Seiten
Format: gebunden
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